Exploring Förster electronic energy transfer in a decoupled anthracenyl-based borondipyrromethene (bodipy) dyad

Literature Information

Publication Date 2012-02-13
DOI 10.1039/C2CP23868C
Impact Factor 3.676
Authors

Dan Bai, Andrew C. Benniston, Jerry Hagon, Helge Lemmetyinen, Nikolai V. Tkachenko, William Clegg, Ross W. Harrington


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Abstract

An anthracenyl-Bodipy dyad containing a triazole bridge, that acts to decouple the two units in the ground state, has been synthesised and structurally characterised. Efficient electronic energy transfer occurs from the anthracenyl-based unit to the Bodipy system in toluene in around 12 ps, and becomes faster in solvents of lower refractive index. The rate of electronic energy transfer is discussed in terms of Förster theory.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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