Photophysics of aminophenyl substituted pyrrolopyrrole cyanines

Literature Information

Publication Date 2011-12-23
DOI 10.1039/C2CP23330D
Impact Factor 3.676
Authors

Simon Wiktorowski, Georg M. Fischer, Martin J. Winterhalder, Ewald Daltrozzo, Andreas Zumbusch


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Abstract

A series of novel pyrrolopyrrole cyanines (PPCys) bearing various aminophenyl substituents at the diketopyrrolopyrrole (DPP) core are presented. Compared to their alkoxyphenyl substituted analogues, these dyes feature additional intense electronic transitions of charge-transfer character which give detailed insight into the optical properties of PPCys. The energetic mixing of the involved orbitals has pronounced effects on the absorption and fluorescence behavior. Protonation of the amino function suppresses these effects and leads to a pronounced increase in fluorescence quantum yield. The photophysics of the dyes can be rationalized by means of a simple energy scheme.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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