Photoionization and imaging spectroscopy of rubidium atoms attached to helium nanodroplets

Literature Information

Publication Date 2012-02-13
DOI 10.1039/C2CP22749E
Impact Factor 3.676
Authors

C. Callegari


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Abstract

Highly excited states of rubidium (Rb) atoms attached to helium (He) nanodroplets are studied by two-photon ionization spectroscopy in combination with electron and ion imaging. We find high yields of RbHe and RbHe2 exciplexes when exciting to the 4D and 6P bands but not at the 6S band, in accord with a direct formation of exciplexes in binding RbHe pair potentials. Photoion spectra and angular distributions are in good agreement with a pseudodiatomic model for the RbHeN complex. Repulsive interactions in the excited states entail fast dissociation followed by ionization of free Rb atoms as well as of RbHe and RbHe2 exciplexes.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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