Macromolecular design of poly(vinyl alcohol) by RAFT polymerization
Literature Information
Publication Date
2011-10-19
DOI
10.1039/C1PY00429H
Impact Factor
5.582
Authors
Anton A. A. Smith, Thomas Hussmann, Joseph Elich, Almar Postma, Marie-Helene Alves, Alexander N. Zelikin
View Original
Abstract
Reversible Addition–Fragmentation chain Transfer polymerization (RAFT) is employed herein to obtain the first example of poly(vinyl alcohol), PVA, with controlled molecular weight and terminal aminegroups thus presenting a flexible tool for materials design and bioconjugation. Furthermore, we demonstrate that RAFT control can be used to facilitate syndiotactic chain propagation and obtain PVA with the highest reported content of syndiotactic dyad (∼78%).
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
2-Methyl-2-propanyl 4-iodo-1-piperidinecarboxylate
CAS Number:
301673-14-3
Molecular Formula:
C10H18INO2
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