Supramolecular design for polymer/titanium oxo-cluster hybrids: an open door to new organic–inorganic dynamers
Literature Information
Publication Date
2011-10-03
DOI
10.1039/C1PY00341K
Impact Factor
5.582
Authors
Costantino Creton
View Original
Abstract
Hybrid materials from organic polymers and inorganic solids often possess enhanced properties compared to their isolated constituents, if intimate mixing is achieved. We report a new approach combining inorganic nanobuilding blocks and supramolecular interactions, exemplified by a titanium oxo-cluster bearing four hydrogen bond acceptors and a telechelic PDMS with two hydrogen bond donors. With these simple components, we demonstrate that well chosen supramolecular interactions can be used to obtain new hybrid dynamers having the intrinsic properties of the inorganic component (such as photochromism) and improved mechanical properties, due to the supramolecular cross-linking of the polymer chains.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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N-[2-Bromo-4-(trifluoromethoxy)phenyl]formamide
CAS Number:
941294-53-7
Molecular Formula:
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