Tribenzotriquinacene-based polymers of intrinsic microporosity
Literature Information
Publication Date
2011-08-11
DOI
10.1039/C1PY00294E
Impact Factor
5.582
Authors
James Vile, Mariolino Carta, C. Grazia Bezzu, Neil B. McKeown
View Original
Abstract
Bowl-shaped tribenzotriquinacene (TBTQ) derivatives containing hydroxyl groups at their peripheral sites are successful monomers for the synthesis of polymers of intrinsic microporosity (PIMs) with examples of both network and non-network PIMs demonstrated. Nitrogen adsorption measurements reveal apparent surface areas in the range of 560ā670 m2 gā1 for the TBTQ-PIMs. A network structure and i-propyl, rather than methyl substitution at the apical site of the TBTQ unit, appear to favour porosity.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Aztreonam USP Related Compound A (Open-ring Aztreonam)
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Molecular Formula:
C13H19N5O9S2
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[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid
CAS Number:
871332-68-2
Molecular Formula:
C11H15BClNO3
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