Synthesis of a controlled three-faced PAMAM particle
Literature Information
Publication Date
2011-07-14
DOI
10.1039/C1PY00146A
Impact Factor
5.582
Authors
Mathieu Arseneault, Philippe Dufour, Isabelle Levesque, Jean-François Morin
View Original
Abstract
We report the synthetic proof-of-concept for a three-faced particle based on a PAMAM dendrimer in which each face bears a different labile protecting group. This new strategy yields a controlled, well-defined and monodisperse dendrimer. To achieve this, a tri-orthogonal strategy was employed through Sonogashira coupling and Cu(I)-catalyzed Huisgen [2 + 3] dipolar cycloaddition (“click” chemistry). The afforded dendrimer is well suited for further development in a variety of fields as each branch can be addressed individually for functionalization.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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