Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks
Literature Information
Publication Date
2011-01-04
DOI
10.1039/C0SC00339E
Impact Factor
9.825
Authors
Abraham M. Shultz, Omar K. Farha, Joseph T. Hupp, SonBinh T. Nguyen
View Original
Abstract
The synthesis of a porous organic polymer (POP) containing free-base porphyrin subunits has been accomplished by the condensation of a bis(phthalic acid)porphyrin with tetra(4-aminophenyl)methane. Metallation by post-synthesis modification affords microporous materials incorporating either Fe or Mn(porphyrins) that have been shown to be active catalysts for both olefin epoxidation and alkane hydroxylation.
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Source Journal
Chemical Science
CiteScore:
14.4
Self-citation Rate:
3.9%
Articles per Year:
1413
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Recommended Compounds
5-Amino-1-(2,4-difluorophenyl)-3-methyl-1H-pyrazole-4-carbonitrile
CAS Number:
1020057-92-4
Molecular Formula:
C11H8F2N4
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