A new synthetic approach to functionalize oxomolybdenum complexes

Literature Information

Publication Date 2013-07-11
DOI 10.1039/C3CE40994E
Impact Factor 3.545
Authors

Zhengguo Lin, Bo Wang, Xiao Feng, Linyuan Fan, Song Yang, Xianqiang Huang, Changwen Hu


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Abstract

A new synthetic approach is developed and nine distinct organic functionalized oxomolybdenum complexes, 1–9, are synthesized and fully characterized. Specifically by altering the functional groups on imidazoles we succeeded in making a series of crystalline structures with unique underlying topologies and/or functionalities. These imidazole derivatives can act as ligands, structural directing agents, counter cations and simultaneously, solvents where the reactions and the crystallization occur.

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CrystEngComm

CrystEngComm
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CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

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