(11alpha,13E)-11-Hydroxy-9,15-dioxoprost-13-en-1-oic acid
CAS Number:
22973-19-9
Molecular Formula:
C20H32O5
Electrodeposition and properties of TEMPO functionalized polythiophene thin films
Literature Information
Publication Date
2010-11-25
DOI
10.1039/C0PY00308E
Impact Factor
5.582
Authors
Tamara K. Kunz, Michael O. Wolf
View Original
Abstract
The modification of an azide-functionalized regioregular polythiophene with TEMPO groups is reported. The TEMPO functionalized polymer is characterized by ESR, ATR-IR, absorption and emission spectroscopies and electrochemical methods. Partial quenching of the polymer emission by the TEMPO groups is observed. The polymer may be electrodeposited onto ITO or carbon electrodes to give thin films. Cyclic voltammetry gives specific charge capacity values of 2.3 mA h g−1 for the TEMPO functionalized polymers, and specific capacitances of 0.8 F g−1 determined by galvanostatic charge/discharge experiments. The reduced charge capacity relative to unfunctionalized polythiophene is attributed to TEMPO induced cleavage and oxidation of the conjugated backbone.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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Molecular Formula:
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