Effect of monomer/oxidant mole ratio on polymerization mechanism, conductivity and spectral characteristics of mechanochemically prepared polypyrrole
Literature Information
Oleg Yu. Posudievsky, Olga A. Kozarenko
The effect of the composition of the initial reaction mixture – pyrrole/oxidant mole ratio – on the mechanism of mechanochemical polymerization of pyrrole was studied. Experimental evidence in favor of the chain mechanism for mechanochemical formation of the highly conducting PPy at high monomer/oxidant mole ratio was first obtained. Interrelation between polymerization mechanism and structure, conductivity and spectral characteristics of the prepared polypyrrole samples was considered.
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