![[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/871/871332-68-2-0e3b.webp "[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure")
[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid
CAS Number:
871332-68-2
Molecular Formula:
C11H15BClNO3
Single site catalysts for stereoselective ring-opening polymerization of lactides
Literature Information
Publication Date
2010-09-08
DOI
10.1039/C0PY00204F
Impact Factor
5.582
Authors
Pieter Jelle Dijkstra, Hongzhi Du, Jan Feijen
View Original
Abstract
Poly(lactide) (PLA) is the most well known biodegradable and biocompatible material among the aliphatic polyesters nowadays explored for biomedical, pharmaceutical and environmental applications. Different poly(lactide)s are distinguished, namely stereoregular PLLA and PDLA, atactic, heterotactic, syndiotactic and stereoblock PLAs. Because the stereochemistry of the monomeric units in the polymer chains plays a decisive role in the mechanical, physical and degradation properties of PLA materials, stereospecific catalysts to prepare different polylactide architectures are a major topic. In this review, after a general introduction on metal catalyzed ring opening polymerization, we mainly focus on single site catalyst systems inducing stereoselective polymerization of lactides.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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