Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers
Literature Information
Publication Date
2010-04-13
DOI
10.1039/C0PY00066C
Impact Factor
5.582
Authors
Bruno Grignard, Trang Phan, Denis Bertin, Didier Gigmes, Christine Jérôme, Christophe Detrembleur
View Original
Abstract
Controlled dispersion nitroxide mediated polymerization (NMP) of methyl methacrylate (MMA) was successfully carried out in supercritical carbon dioxide (scCO2) in the presence of a CO2-philic perfluorinated stabilizer generated “in situ”. This is an efficient green approach for preparing free flowing PMMA powder consisting of small sized microspheres.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Ethyl 4-[8-chloro(5,5,6,6,7-~2~H_5_)-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene]-1-piperidinecarboxylate
CAS Number:
1020719-57-6
Molecular Formula:
C22H18D5ClN2O2
![6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one structure](https://static.chemtradehub.com/structs/926/926319-53-1-2287.webp "6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one structure")
6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one
CAS Number:
926319-53-1
Molecular Formula:
C17H14BrNO4
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