Reusable polystyrene-supported Pdcatalyst for Mizoroki–Heck reactions with extremely low amounts of supported Pd

Literature Information

Publication Date 2010-09-09
DOI 10.1039/C0OB00523A
Impact Factor 3.876
Authors

Carine Diebold, Stéphane Schweizer, Jean-Michel Becht, Claude Le Drian


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Abstract

In this communication, we report that by running Mizoroki–Heck reactions of various aryl iodides in toluene–DMF, only extremely low amounts of supported Pd (0.04 mequiv.) are required to obtain almost quantitative yields. The catalyst was reused successfully up to three times.

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Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
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Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

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