Water-supported organized structures based on wedge-shaped amphiphilic derivatives of dipyrrolyldiketone boron complexes

Literature Information

Publication Date 2011-01-05
DOI 10.1039/C0CP02294B
Impact Factor 3.676
Authors

Nazuki Eifuku, Yohei Haketa, Yoshihiro Ito


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Abstract

Wedge-shaped amphiphilic derivatives of 1,3-dipyrrolyl-1,3-propanedione boron complexes, with one or no aliphatic chains attached at one aryl moiety and three hydrophilic chains at the other, exhibited formation of assembled structures in aqueous solutions. UV/vis, fluorescence and DLS analyses suggested that the wedge-shaped amphiphiles exist in assembled modes in the solution state, and TEM measurements revealed that a balance of hydrophobic and hydrophilic moieties in the amphiphiles is crucial for the formation of organized structures in aqueous solutions as evidenced by the formation of spherical and cylindrical micelles.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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