Photoionization-induced large-amplitude pendular motion in phenol+–Kr
Literature Information
Mitsuhiko Miyazaki, Akihiro Takeda, Shun-ichi Ishiuchi, Makoto Sakai, Otto Dopfer, Masaaki Fujii
The dynamics of the intermolecular motion of the phenol+–Kr cation generated by photoionization of the neutral π-structure is probed by picosecond time-resolved infrared spectroscopy. The spectrum at zero delay displays only the free OH stretch band of the π-structure. The appearance of the hydrogen-bonded OH stretch band of the H-structure after a few ps is due to ionization-induced π → H site switching. Spectra at long delay (>20 ns) show that the Kr atom delocalizes from one π-site of the aromatic ring to the opposite π-site via the OH-site, like a pendular motion in the classical picture.
Recommended Journals

Current Opinion in Solid State & Materials Science

Journal of Saudi Chemical Society

Chemical Communications

New Journal of Chemistry

Current Opinion in Colloid & Interface Science

Russian Journal of Bioorganic Chemistry

Chemistry Education Research and Practice

Russian Journal of Applied Chemistry

Russian Chemical Bulletin

Saudi Pharmaceutical Journal
Related Literature
The role of energy cost on accuracy, sensitivity, specificity, speed and adaptation of T cell foreign and self recognition
Gyubaek Shin
DOI: 10.1039/D0CP02422H
Magnetic anisotropy in YbIII complex candidates for molecular qubits: a theoretical analysis
Martín Amoza, Silvia Gómez-Coca, Eliseo Ruiz
DOI: 10.1039/D0CP05422D
Thermal decomposition and isomerization of furfural and 2-pyrone: a theoretical kinetic study
Saddam Al-Hammadi, Gabriel da Silva
DOI: 10.1039/D0CP05523A
A general approach to study molecular fragmentation and energy redistribution after an ionizing event
Suvasthika Indrajith, Alicja Domaracka, Patrick Rousseau, Bernd A. Huber, Paola Bolognesi, Robert Richter, Lorenzo Avaldi, Marta Łabuda
DOI: 10.1039/D0CP04890A
Anti-alignment driven dynamics in the excited states of molecules under strong fields
Ignacio R. Sola
DOI: 10.1039/D0CP05692H
Re-examining the electronic structure of fluorescent tetra-silver clusters in zeolites
DOI: 10.1039/D0CP05105E
Elastic properties of superionic cubic silver sulfide β-Ag2S
DOI: 10.1039/D0CP04761A
Development of coarse-grained force field for alcohols: an efficient meta-multilinear interpolation parameterization algorithm
Junjie Song, Ying Yang, Lianghui Gao
DOI: 10.1039/D0CP05503D
You might also like
How is Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) typically synthesized?
Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) can be synth...
What regulatory guidelines apply to 5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2)?
5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2) is subject to various regula...
What are the physical and chemical properties of (1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid (CAS: 223418-73-3)?
(1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid is a white...
How should waste containing Sulfocostunolide A (CAS: 1016983-51-9) be handled?
Waste containing Sulfocostunolide A (CAS: 1016983-51-9) should be handled with c...
What precautions should be taken when handling Murraxocin (CAS: 88478-44-8)?
When handling Murraxocin (CAS: 88478-44-8), ensure proper personal protective eq...
What are the physical and chemical properties of Formvar (CAS: 63148-64-1)?
Formvar (CAS: 63148-64-1) is an alkyd resin characterized by a high molecular we...
Is (S)-4-benzyl-2-((benzyloxy)methyl)morpholine (CAS: 205242-66-6) safe?
(S)-4-benzyl-2-((benzyloxy)methyl)morpholine is generally safe when handled with...
What industries use Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3)?
Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3) is p...
Is 2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) safe?
2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) is generally con...
How is 3-(4-Bromophenyl)-2-methylpropanoic acid (CAS: 66735-01-1) typically synthesized?
3-(4-Bromophenyl)-2-methylpropanoic acid is synthesized through a multi-step pro...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




