Picosecond X-ray absorption measurements of the ligand substitution dynamics of Fe(CO)5 in ethanol
Literature Information
Brian Ahr, Matthieu Chollet, Bernhard Adams, Elizabeth M. Lunny, Christopher M. Laperle, Christoph Rose-Petruck
Ultrafast X-ray absorption near edge spectroscopy has been carried out for photo excited iron pentacarbonyl in ethanol with 2 picosecond resolution. A temporal resolution limited dissociation process was observed, followed by the formation of the mono-substituted complex Fe(CO)4EtOH within a few tens of picoseconds. The measurements have been carried out with a newly developed X-ray absorption instrument at station 7 ID-C of the Advanced Photon Source. The results show that single picosecond temporal resolution can be achieved at a synchrotron beam line.
Recommended Journals
Related Literature
A new understanding of the photocatalytic mechanism of the direct Z-scheme g-C3N4/TiO2 heterostructure
Bei Cheng
DOI: 10.1039/C6CP06147H
Hydrogen bonds vs. π-stacking interactions in the p-aminophenol⋯p-cresol dimer: an experimental and theoretical study
M. C. Capello, F. J. Hernández, C. Dedonder-Lardeux, C. Jouvet, G. A. Pino
DOI: 10.1039/C6CP06352G
Influences of heterogeneous native contact energy and many-body interactions on the prediction of protein folding mechanisms
Zhuqing Zhang, Yanhua Ouyang, Tao Chen
DOI: 10.1039/C6CP06181H
Thermodynamics and kinetics of carbon deposits on cobalt: a combined density functional theory and kinetic Monte Carlo study
Antonius P. J. Jansen, Ravi Agrawal, Leonardo Spanu
DOI: 10.1039/C6CP04719J
A theoretical study of the atmospherically important radical–radical reaction BrO + HO2; the product channel O2(a1Δg) + HOBr is formed with the highest rate
Ronald Chow, Daniel K. W. Mok, John M. Dyke
DOI: 10.1039/C6CP05877A
Growth patterns and structural motifs of cadmium clusters with up to 60 atoms: disordered or not?
Stephan Kohaut
DOI: 10.1039/C6CP04948F
High-efficiency p–n junction oxide photoelectrodes for photoelectrochemical water splitting
Lu Yan
DOI: 10.1039/C6CP06536H
Trapped in the coordination sphere: nitrate ion transfer driven by the cerium(iii/iv) redox couple
Ross J. Ellis, Mrinal K. Bera, Benjamin Reinhart, Mark R. Antonio
DOI: 10.1039/C6CP06528G
Preferential solvation and ion association properties in aqueous dimethyl sulfoxide solutions
Anand Narayanan Krishnamoorthy, Johannes Zeman, Christian Holm, Jens Smiatek
DOI: 10.1039/C6CP05909K
Excited-state intramolecular proton transfer and conformational relaxation in 4′-N,N-dimethylamino-3-hydroxyflavone doped in acetonitrile crystals
Kazuki Furukawa, Norifumi Yamamoto, Kazuyuki Hino, Hiroshi Sekiya
DOI: 10.1039/C6CP04322D
You might also like
How is Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) typically synthesized?
Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) can be synth...
What regulatory guidelines apply to 5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2)?
5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2) is subject to various regula...
What are the physical and chemical properties of (1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid (CAS: 223418-73-3)?
(1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid is a white...
How should waste containing Sulfocostunolide A (CAS: 1016983-51-9) be handled?
Waste containing Sulfocostunolide A (CAS: 1016983-51-9) should be handled with c...
What precautions should be taken when handling Murraxocin (CAS: 88478-44-8)?
When handling Murraxocin (CAS: 88478-44-8), ensure proper personal protective eq...
What are the physical and chemical properties of Formvar (CAS: 63148-64-1)?
Formvar (CAS: 63148-64-1) is an alkyd resin characterized by a high molecular we...
Is (S)-4-benzyl-2-((benzyloxy)methyl)morpholine (CAS: 205242-66-6) safe?
(S)-4-benzyl-2-((benzyloxy)methyl)morpholine is generally safe when handled with...
What industries use Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3)?
Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3) is p...
Is 2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) safe?
2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) is generally con...
How is 3-(4-Bromophenyl)-2-methylpropanoic acid (CAS: 66735-01-1) typically synthesized?
3-(4-Bromophenyl)-2-methylpropanoic acid is synthesized through a multi-step pro...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














