Solving the spectroscopic phase: imaging excited wave packets and extracting excited state potentials from fluorescence data

Literature Information

Publication Date 2010-11-10
DOI 10.1039/C0CP01417F
Impact Factor 3.676
Authors

Xuan Li, Cian Menzel-Jones, David Avisar


View Original

Abstract

We develop an inversion scheme for obtaining the signs of transition-dipole amplitudes from fluorescence line intensities. Using the amplitudes thus obtained we show how to extract highly accurate excited state potential(s) and the transition-dipole(s) as a function of inter-nuclear displacements. The same dipole amplitudes can also be used to extract the phase and amplitude of unknown time-evolving wave packets, in essentially a quantum non-demolition manner. The procedure, which is demonstrated for the A(1∑+u) and B(1Πu) states of the Na2 molecule, is shown to yield reliable results even when we are given incomplete or uncertain data. We also demonstrate the success of our approach in extracting double minimum potentials. The inversion scheme is in principle applicable to any polyatomic molecule.

Related Literature

Complexation induced aggregation and deaggregation of acridine orange with sulfobutylether-β-cyclodextrin

Mhejabeen Sayed, Shruti Jha, Haridas Pal

2017-08-17 Paper

DOI: 10.1039/C7CP03135A

Extending charge separation lifetime and distance in patterned dye-sensitized SnO2–TiO2 μm-thin films

Valeria Saavedra Becerril, Elin Sundin, Mokhtar Mapar, Maria Abrahamsson

2017-08-10 Paper

DOI: 10.1039/C7CP04486K

The excited-state decay mechanism of 2,4-dithiothymine in the gas phase, microsolvated surroundings, and aqueous solution

Bin-Bin Xie, Qian Wang, Wei-Wei Guo, Ganglong Cui

2017-02-16 Paper

DOI: 10.1039/C7CP00478H

Structural, optical and phonon properties of formate-based MOF phosphors with ethylammonium cations

M. Ptak, K. Pasińska, P. Głuchowski, A. Łukowiak, A. Ciupa

2017-08-14 Paper

DOI: 10.1039/C7CP04005A

On the critical Casimir interaction between anisotropic inclusions on a membrane

Jorge Benet, Fabien Paillusson, Halim Kusumaatmaja

2017-08-25 Paper

DOI: 10.1039/C7CP03874G

Optical properties and magnetic flux-induced electronic band tuning of a T-graphene sheet and nanoribbon

Arka Bandyopadhyay, Atanu Nandy, Arunava Chakrabarti, Debnarayan Jana

2017-07-24 Paper

DOI: 10.1039/C7CP03983B

Polarization transfer efficiency in PHIP experiments

M. Emondts, J. F. P. Colell, B. Blümich

2017-08-01 Communication

DOI: 10.1039/C7CP04296E

Approaching complexity of alkyl hydrogenation on Pd via density-functional modelling

Sergey M. Kozlov, Georgi N. Vayssilov

2017-07-18 Paper

DOI: 10.1039/C7CP03516K

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.