Real space functions from experimental small angle scattering data

Literature Information

Publication Date 2011-02-18
DOI 10.1039/C0CP01332C
Impact Factor 3.676
Authors

Alexander Bergmann, Otto Glatter


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Abstract

A model free evaluation of small angle scattering data of interacting particles results in real space curves that are often difficult to interpret. It is then easier to use a model for the inter and/or the intra particle effects. Such a procedure requires the selection of appropriate models. The selection of the correct model is facilitated by interpreting parts of the purely model free real space results of the scattering data. The corresponding functions for hard, charged, and attractive spheres are simulated as well as the curves of spheres in BCC crystalline order and of cylinders in hexagonal order. The simulated results are compared to experimental data obtained from concentrated emulsions. Estimations for particle diameter, type of interaction, next neighbour distance, and volume fraction can be deduced from most of the data.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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