Two-proton migration in 1,3-butadiene in intense laser fields
Literature Information
Tomoya Okino, Katsunori Nakai, Kaoru Yamanouchi, Stefan Roither, Xinhua Xie, Daniil Kartashov, Li Zhang, Andrius Baltuska, Markus Kitzler
Ultrafast proton migration in 1,3-butadiene in an intense laser field (40 fs, 4.5 × 1014 W cm−2) is investigated by using Coulomb explosion coincidence momentum imaging. The spatial distribution maps of a migrating proton reconstructed for the two three-body Coulomb explosion pathways, C4H63+ → H+ + CH3+ + C3H2+ and C4H63+ → H+ + C2H+ + C2H4+, reveal that two protons migrate within a 1,3-butadiene molecule, prior to the three body decomposition.
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