Two-proton migration in 1,3-butadiene in intense laser fields

Literature Information

Publication Date 2010-08-23
DOI 10.1039/C0CP00628A
Impact Factor 3.676
Authors

Tomoya Okino, Katsunori Nakai, Kaoru Yamanouchi, Stefan Roither, Xinhua Xie, Daniil Kartashov, Li Zhang, Andrius Baltuska, Markus Kitzler


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Abstract

Ultrafast proton migration in 1,3-butadiene in an intense laser field (40 fs, 4.5 × 1014 W cm−2) is investigated by using Coulomb explosion coincidence momentum imaging. The spatial distribution maps of a migrating proton reconstructed for the two three-body Coulomb explosion pathways, C4H63+ → H+ + CH3+ + C3H2+ and C4H63+ → H+ + C2H+ + C2H4+, reveal that two protons migrate within a 1,3-butadiene molecule, prior to the three body decomposition.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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