Mechanism study on inhibited Ru(bpy)32+ electrochemiluminescence between coreactants
Literature Information
Lingling Xue, Bin Qiu, Zhenyu Lin, Donghwan Kim, Guonan Chen
Electrochemiluminescence (ECL) derived from Ru(bpy)32+ and its derivatives has been proven to be useful in diverse areas of analytical chemistry. Up to date most of the applications are based on coreactant ECL technology. However, little attention has been paid to the ECL inhibition between coreactants. In this paper, the ECL inhibition behavior between coreactants was systematically investigated. The results showed that ECL inhibition happened not only within the same type of coreactants, but also between two different types of coreactants. Interestingly, for some weak coreactants, the detection methods based on ECL inhibition were much more sensitive than those based on ECL enhancement. Therefore, it is envisioned to establish sensitive inhibited ECL detection methods for these weak coreactants. A possible ECL inhibition mechanism related to the consumption of coreactant intermediates without light emission is proposed.
Related Literature
Encapsulation property of hyperbranched polyglycerols as prospective drug delivery systems
Ting Yin, Ke Li, Ruibin Wang, Yantian Chen, Lili Jing
DOI: 10.1039/C7PY01419H
Dual-responsive biocompatible microgels as high loaded cargo: understanding of encapsulation/release driving forces by NMR NOESY
Abdeld Khoukh, Kamel Chougrani, Valérie Alard
DOI: 10.1039/C7PY02111A
Thermo- and redox-responsive dendronized polymer hydrogels
Xiacong Zhang, Yu Yin, Jiatao Yan, Afang Zhang
DOI: 10.1039/C7PY01284E
Photosensitive poly(o-nitrobenzyloxycarbonyl-l-lysine)-b-PEO polypeptide copolymers: synthesis, multiple self-assembly behaviors, and the photo/pH-thermo-sensitive hydrogels
Pan Li, Jiacheng Zhang, Chang-Ming Dong
DOI: 10.1039/C7PY01574G
A first study on copolymers of a methacrylate containing the 2-(hydroxyimino)aldehyde group and OEGMA. RAFT polymerization and assessment of thermal and photoresponsive polymer behavior
Francesca D'Acunzo, Mariangela Clemente, Giampiero Proietti
DOI: 10.1039/C7PY00975E
Stimuli responsive self-healing polymers: gels, elastomers and membranes
Adérito J. R. Amaral, George Pasparakis
DOI: 10.1039/C7PY01386H
Morphology control in polymerised high internal phase emulsion templated via macro-RAFT agent composition: visualizing surface chemistry
R. D. Arrua, T. Rodemann, T. Ohigashi, N. Kosugi, S. C. Thickett, E. F. Hilder
DOI: 10.1039/C7PY01770G
Conjugate substitution and addition of α-substituted acrylate: a highly efficient, facile, convenient, and versatile approach to fabricate degradable polymers by dynamic covalent chemistry
Yasuhiro Kohsaka, Takumi Miyazaki, Keito Hagiwara
DOI: 10.1039/C7PY02114C
Metallocene influence on poly(cyclosilane) structure and properties
Carlton P. Folster, Rebekka S. Klausen
DOI: 10.1039/C8PY00312B
Bio-inspired peptide decorated dendrimers for a robust antibacterial coating on hydroxyapatite
Xiao Yang, Libang He, Xinyuan Xu, Yanpeng Liu, Yuebo Liu, Yuan Gao, Qin Huang, Kunneng Liang, Chunmei Ding, Jiyao Li, Changsheng Zhao, Jianshu Li
DOI: 10.1039/C7PY00811B
You might also like
What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?
When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...
Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?
4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...
How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?
Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...
What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?
5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...
How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?
Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...
What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?
4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...
How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?
Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...
What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?
6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...
Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?
(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...
What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?
7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![tert-butyl 8-benzyl-2,8-diazaspiro[4.5]decane-2-carboxylate structure tert-butyl 8-benzyl-2,8-diazaspiro[4.5]decane-2-carboxylate structure](https://static.chemtradehub.com/structs/336/336191-16-3-bb55.webp)


![(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure (R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure](https://static.chemtradehub.com/structs/159/1595319-98-4-33e7.webp)