Comment on “An explanation for the charge on water's surface” by A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994

Literature Information

Publication Date 2010-09-23
DOI 10.1039/C001492C
Impact Factor 3.676
Authors

Dominik Horinek, Richard Buchner, Bernd Winter, Pavel Jungwirth


View Original

Abstract

Gray-Weale and Beattie’s rationalization of the negative charge observed on the surface of water in terms of accumulation of OH− is based on the supposedly uniquely large dielectric decrement of hydroxide solutions [A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994]. We challenge this rationalization and point to another ion, namely fluoride, which has a comparable dielectric decrement and size and which is repelled from the surface of water.

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