Oriented growth of the functionalized metal–organic framework CAU-1 on –OH- and –COOH-terminated self-assembled monolayers

Literature Information

Publication Date 2010-04-13
DOI 10.1039/B924657F
Impact Factor 3.676
Authors

Florian Hinterholzinger, Camilla Scherb, Tim Ahnfeldt, Norbert Stock, Thomas Bein


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Abstract

The oriented growth of the amino-functionalized metal–organic framework [Al4(OH)2(OCH3)4(H2N-bdc)3]·xH2O (named CAU-1; CAU = Christian-Albrechts-University) on different self-assembled monolayers (SAMs) is reported. Gold substrates were modified with both 16-mercaptohexadecanol and 16-mercaptohexadecanoic acid SAMs and immersed in a pre-treated crystallization solution. The different terminal functionalities and synthesis parameters result in the direct surface growth of CAU-1 crystals along preferred crystallographic orientations. While for the OH-terminated SAMs a preferential attachment of the CAU-1 crystals either in [011] or [002] direction is observed (depending on the reaction conditions), highly oriented crystal growth in [002] orientation was obtained on the carboxylic acid functionalized SAMs.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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