Redox-induced partner radical formation and its dynamic balance with radical dimer in cucurbit[8]uril
Literature Information
Tongyan Zhang, Shiguo Sun, Fengyu Liu, Jiangli Fan, Licheng Sun, Xiaojun Peng
N-(4-Hydroxy-phenoxyethyl)-N′-ethyl-4,4′-bipyridium (1) can form a stable 1 : 1 inclusion complex with CB[8] in aqueous solution, in which the hydroxyphenol (HP) moiety is back-folded and inserted together with the viologen moiety into the cavity of CB[8]. When the ethyl viologen dication (EV2+) in 1 is reduced, chemically or electrochemically, an intramolecular partner radical (EV+˙-HP)/CB[8] can be detected, meanwhile, a dynamic balance between the partner radical and the intermolecular radical dimer (EV+˙-HP)2/CB[8] can be observed.
Related Literature
Triplet state promoted reaction of SO2 with H2O by competition between proton coupled electron transfer (pcet) and hydrogen atom transfer (hat) processes
Josep M. Anglada, Marilia T. C. Martins-Costa, Joseph S. Francisco, Manuel F. Ruiz-López
DOI: 10.1039/C9CP01105F
Excited-state dynamics of heteroleptic copper(i) photosensitizers and their electrochemically reduced forms containing a dipyridophenazine moiety – a spectroelectrochemical transient absorption study
Linda Zedler, Michael Karnahl
DOI: 10.1039/C9CP00412B
Peroxy self-reaction leading to the formation of furfural
Audrey R. Smith, Simone Di Muzio, Fabio Ramondo, Giovanni Meloni
DOI: 10.1039/C8CP07571A
Proton transport properties of proton-conducting phosphate glasses at their glass transition temperatures
Takahisa Omata, Satoshi Tsukuda, Tomohiro Ishiyama, Junji Nishii, Toshiharu Yamashita, Hiroshi Kawazoe
DOI: 10.1039/C9CP01502G
Multiple glass transitions in vapor-deposited orientational glasses of the most fragile plastic crystal Freon 113
A. Vila-Costa, J. Ràfols-Ribé, M. Gonzalez-Silveira, A. Lopeandía, J. Ll. Tamarit, J. Rodríguez-Viejo
DOI: 10.1039/C9CP00976K
Unexpected chalcogen bonds in tetravalent sulfur compounds
Antonio Franconetti, David Quiñonero, Antonio Frontera, Giuseppe Resnati
DOI: 10.1039/C9CP01033E
Effect of bovine serum albumin on tartrate-modified manganese ferrite nano hollow spheres: spectroscopic and toxicity study
Indranil Chakraborty, Urmila Saha, Dipika Mandal, Suprabhat Mukherjee, Nikhilesh Joardar, Santi P. Sinha Babu, Gopinatha Suresh Kumar, Kalyan Mandal
DOI: 10.1039/C9CP01877H
A competitive hopping model for carrier transport in disordered organic semiconductors
Chongguang Zhao, Chen Li
DOI: 10.1039/C9CP01243E
Understanding the size effects on the electronic structure of ThO2 nanoparticles
Tatiana V. Plakhova, Anna Yu. Romanchuk, Stephan Weiss, Anna Efimenko, Christoph J. Sahle, Sergei M. Butorin, Stepan N. Kalmykov
DOI: 10.1039/C9CP01283D
Hydrogen quenches the size effects in carbon clusters
José I. Martínez, Julio A. Alonso
DOI: 10.1039/C9CP01114E
You might also like
What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?
When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...
What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?
4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...
How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?
Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...
What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?
(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...
What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?
2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...
Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?
There are alternative reagents that can be used in synthesis instead of (E)-4-(t...
What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?
[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...
What is the market or research trend for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]{[(4-methylphenyl)sulfonyl]oxy}acetate (CAS: 166249-17-8)?
The market and research trends for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4...
What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?
The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...
What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?
4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![2-Hydroxy-4-[({[(4-methylphenyl)sulfonyl]oxy}acetyl)amino]benzoic acid structure 2-Hydroxy-4-[({[(4-methylphenyl)sulfonyl]oxy}acetyl)amino]benzoic acid structure](https://static.chemtradehub.com/structs/501/501919-59-1-579f.webp)

![(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one structure (1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one structure](https://static.chemtradehub.com/structs/102/10293-06-8-dd8a.webp)
