Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature

Literature Information

Publication Date 2009-09-04
DOI 10.1039/B914736E
Impact Factor 6.222
Authors

Ghayoor A. Chotana, Britt A. Vanchura, II, Man Kin Tse, Richard J. Staples, Robert E. Maleczka, Jr, Milton R. Smith, III


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Abstract

Five-coordinate boryl complexes relevant to Ir mediated C–H borylations have been synthesized, providing a glimpse of the most fundamental step in the catalytic cycle for the first time.

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