Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature
Literature Information
Ghayoor A. Chotana, Britt A. Vanchura, II, Man Kin Tse, Richard J. Staples, Robert E. Maleczka, Jr, Milton R. Smith, III
Five-coordinate boryl complexes relevant to Ir mediated C–H borylations have been synthesized, providing a glimpse of the most fundamental step in the catalytic cycle for the first time.
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