Oligosilylated group 4 titanocenes in the oxidation state +3

Literature Information

Publication Date 2009-08-13
DOI 10.1039/B910637E
Impact Factor 6.222
Authors

Michaela Zirngast, Ulrich Flörke, Judith Baumgartner, Christoph Marschner


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Abstract

Reactions of oligosilylanions with Cp2TiCl2 led to the formation of ate-complexes of silylated titanocenes, which form upon silylation of the intermediate K[Cp2TiCl2]·18-crown-6.

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