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The preparation of the MF6− (M = As, Sb) salts of 1,4-benzoquinodal bridged bis-1,3,2-dithiazolylium utilizing the cycloaddition and oxidative dehydrogenation chemistry of SNSMF6 and observation of a hybrid semiquinoidal–thiazyl radical-cation by EPR
Literature Information
Publication Date
2009-08-25
DOI
10.1039/B910338D
Impact Factor
6.222
Authors
Andreas Decken, Aaron Mailman, Jack Passmore
View Original
Abstract
SNSMF6 (M = As, Sb) reacts with 1,4-benzoquinone in a series of cycloaddition and oxidative dehydrogenation reactions to give 3 (MF6)2 which on reduction with CsI yields the unique semiquinodal–thiazyl radical-cation (3++˙) as observed by X-band solution ESR and supported by DFT calculations.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
(E)-2-methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-3-en-2-ol
CAS Number:
581802-26-8
Molecular Formula:
C11H21BO3
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