The preparation of the MF6− (M = As, Sb) salts of 1,4-benzoquinodal bridged bis-1,3,2-dithiazolylium utilizing the cycloaddition and oxidative dehydrogenation chemistry of SNSMF6 and observation of a hybrid semiquinoidal–thiazyl radical-cation by EPR

Literature Information

Publication Date 2009-08-25
DOI 10.1039/B910338D
Impact Factor 6.222
Authors

Andreas Decken, Aaron Mailman, Jack Passmore


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Abstract

SNSMF6 (M = As, Sb) reacts with 1,4-benzoquinone in a series of cycloaddition and oxidative dehydrogenation reactions to give 3 (MF6)2 which on reduction with CsI yields the unique semiquinodal–thiazyl radical-cation (3++˙) as observed by X-band solution ESR and supported by DFT calculations.

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