Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

Literature Information

Publication Date 2009-07-22
DOI 10.1039/B908378B
Impact Factor 6.222
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Abstract

The nucleophilicaddition reaction of diazo-compound derived anions or enolates with electrophilic CO and CN bonds have been summarized. The subsequent reactions of the addition products demonstrate diverse reactivities of the diazocarbonyl compounds bearing other functional groups and their potential in organic synthesis. Asymmetric catalysis is also possible with diazocarbonyl compounds as nucleophiles.

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