A W-band pulsed EPR/ENDOR study of CoIIS4 coordination in the Co[(SPPh2)(SPiPr2)N]2 complex
Literature Information
Silvia Sottini, Guinevere Mathies, Peter Gast, Dimitrios Maganas, Panayotis Kyritsis, Edgar J.J. Groenen
Spin-echo detection at 95 GHz enables an electron-paramagnetic-resonance study of a cobalt complex with a bio-mimetic coordination of the transition metal by four sulfur atoms. A magnetically diluted single crystal of the complex has been investigated in great detail. Electron-nuclear double-resonance signals were observed of ligand nuclei and complete hyperfine tensors of the distinct phosphorus nuclei were derived, assigned and discussed.
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