A W-band pulsed EPR/ENDOR study of CoIIS4 coordination in the Co[(SPPh2)(SPiPr2)N]2 complex

Literature Information

Publication Date 2009-07-08
DOI 10.1039/B905726A
Impact Factor 3.676
Authors

Silvia Sottini, Guinevere Mathies, Peter Gast, Dimitrios Maganas, Panayotis Kyritsis, Edgar J.J. Groenen


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Abstract

Spin-echo detection at 95 GHz enables an electron-paramagnetic-resonance study of a cobalt complex with a bio-mimetic coordination of the transition metal by four sulfur atoms. A magnetically diluted single crystal of the complex has been investigated in great detail. Electron-nuclear double-resonance signals were observed of ligand nuclei and complete hyperfine tensors of the distinct phosphorus nuclei were derived, assigned and discussed.

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Contents

Front/Back Matter

DOI: 10.1039/C0CP90074E

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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