Nanoenergetic materials: boron nanoparticles from the pyrolysis of decaborane and their functionalisation
Literature Information
Brian J. Bellott, Wontae Noh, Ralph G. Nuzzo, Gregory S. Girolami
The surfaces of boron nanoparticles 10–150 nm in diameter, prepared by gas phase pyrolysis of decaborane vapour at 1 atm and 700–900 °C, can be halogenated by treatment with Br2 or XeF2; the surface halogenation somewhat increases the onset temperature for the oxidation of the particles under O2.
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