Ag(i)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile
Literature Information
Publication Date
2009-04-06
DOI
10.1039/B902162K
Impact Factor
6.222
Authors
Li-Rong Guo, Song-Song Bao, Yi-Zhi Li, Li-Min Zheng
View Original
Abstract
A general approach to obtain pyrophosphonates is achieved by reacting arylphosphonic acids with AgNO3 in CH3CN under solvothermal conditions; the process is coupled with the C–C bond cleavage of acetonitrile and the formation of novel complexes [Agn(RPO2(O)O2PR)m](CN); the mechanism of the process is proposed.
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Source Journal
Chemical Communications
CiteScore:
8.6
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4.7%
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2458
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Recommended Compounds
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10-(1-Azabicyclo[2.2.2]oct-3-ylmethyl)-10H-phenothiazine
CAS Number:
29216-28-2
Molecular Formula:
C20H22N2S
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