Electrons from hydrogen

Literature Information

Publication Date 2009-03-24
DOI 10.1039/B900297A
Impact Factor 6.222
Authors


View Original

Abstract

The growing need for hydrogen-based fuel cells has driven research into hydrogenase (H2ase)—a natural enzyme that catalyses the extraction of electrons from H2 in water under ambient conditions. Unfortunately, the exact mechanism by which H2ase achieves this feat has remained a matter of some controversy until now, with many mechanisms being inconsistent with experimental data. Recently, however, we have been able to produce a successful catalytic mimic of H2ase that replicates key aspects of it. This paper begins with an overview of the research from many groups that preceded this discovery, followed by a detailed analysis of the key points that set our unique functional model apart—that is to say a proton-like “hydride” species, a surprisingly low-valent NiIRuI complex and the key insight that two molecules of H2 are required for electron extraction.

Related Literature

Water and ammonia on Cu{110}: comparative structure and bonding

Stephen J. Jenkins

2013-02-04 Paper

DOI: 10.1039/C3CP42658K

Impact of surface steps and oxygen pre-coverage on the adsorption of methylamine on gold

April D. Lewoczko, Joseph J. BelBruno

2013-02-11 Paper

DOI: 10.1039/C3CP44471F

Towards low-cost flexible substrates for nanoplasmonic sensing

Lakshminarayana Polavarapu

2012-12-11 Perspective

DOI: 10.1039/C2CP43642F

Electron induced reactions of surface adsorbed tungsten hexacarbonyl (W(CO)6)

Samantha G. Rosenberg, Michael Barclay, D. Howard Fairbrother

2013-01-30 Paper

DOI: 10.1039/C3CP43902J

Formation and decay of a compressed phase of 4,4′-biphenyldicarboxylic acid on Cu(001)

Daniel Schwarz, Raoul van Gastel, Harold J. W. Zandvliet, Bene Poelsema

2013-02-07 Paper

DOI: 10.1039/C3CP00049D

Photobleaching of quantum dots by non-resonant light

Xingbo Shi, Yang Tu, Xiaojun Liu, Edward S. Yeung, Hongwei Gai

2013-01-14 Communication

DOI: 10.1039/C3CP43668C

New insights into two-photon absorption properties of functionalized aza-BODIPY dyes at telecommunication wavelengths: a theoretical study

Jilong Zhang, Kai Li, Xiaobo Sun, Zhijian Wu, Aimin Ren, Jikang Feng

2013-01-28 Paper

DOI: 10.1039/C3CP44435J

Back cover

Cover

DOI: 10.1039/C3CP90040A

Excited state interactions between flurbiprofen and tryptophan in drug–protein complexes and in model dyads. Fluorescence studies from the femtosecond to the nanosecond time domains

Ignacio Vayá, Paula Bonancía, M. Consuelo Jiménez, Dimitra Markovitsi, Thomas Gustavsson, Miguel A. Miranda

2013-01-23 Paper

DOI: 10.1039/C3CP43847C

CCSD(T) level interaction energy for halogen bond between pyridine and substituted iodobenzenes: origin and additivity of substituent effects

Seiji Tsuzuki, Tadafumi Uchimaru, Akihiro Wakisaka, Taizo Ono, Takaaki Sonoda

2013-02-27 Paper

DOI: 10.1039/C3CP43693D

You might also like

Compound Q&A

How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?

Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...

100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A

How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?

7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...

1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A

What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?

2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...

124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A

Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?

1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...

1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A

What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?

The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...

113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A

What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?

3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...

163271-80-53-(Triisopropylsilyl...
Compound Q&A

What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?

6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...

81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A

How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?

Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...

885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A

What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?

N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...

55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A

What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?

6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...

1036756-15-66-Bromo-8-fluoro-2-q...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.