Formation and decay of a compressed phase of 4,4′-biphenyldicarboxylic acid on Cu(001)

Literature Information

Publication Date 2013-02-07
DOI 10.1039/C3CP00049D
Impact Factor 3.676
Authors

Daniel Schwarz, Raoul van Gastel, Harold J. W. Zandvliet, Bene Poelsema


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Abstract

The molecular arrangement of 4,4′-biphenyldicarboxylic acid (BDA) on Cu(001) has been studied at high coverage and relatively high temperature (∼400 K) using Low Energy Electron Microscopy, LEEM, and selected area diffraction, μLEED. Next to the previously reported c(8 × 8) structure, we also observe a compressed phase with a superstructure in matrix notation. All four equivalent (rotational and mirror) domains are equally populated. Both the c(8 × 8) and the compressed phase are confined to the first layer and the latter has a 14% higher density compared to the c(8 × 8) phase. Remarkably, this compressed phase is stable only during deposition and decays after interruption of the deposition. Apparently, the density of physisorbed admolecules on top of the c(8 × 8) layer has to be above a relevant threshold to allow the formation of the compressed phase.

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