Asymmetric tandem Michael addition–ylide olefination reaction for the synthesis of optically active cyclohexa-1,3-diene derivatives
Literature Information
Long-Wu Ye, Shou-Bing Wang, Qing-Gang Wang, Xiu-Li Sun, Yong Tang, Yong-Gui Zhou
The reaction of a crotonate-derived chiral phosphonium salt with α,β-unsaturated carbonyl compounds in the presence of Cs2CO3 affords optically active cyclohexa-1,3-diene derivatives with up to 90% ee in good yields.
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