Ion transfer across a liquid membrane. General solution for the current-potential response of any voltammetric technique

Literature Information

Publication Date 2009-01-12
DOI 10.1039/B816843C
Impact Factor 3.676
Authors

A. Molina, C. Serna, J. Gonzalez, J. A. Ortuño, E. Torralba


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Abstract

An explicit analytical equation applicable to the study of reversible ion transfer at systems with two liquid/liquid polarizable interfaces is presented. This expression is valid for any multipotential step technique, which are all very adequate for the determination of standard transfer potentials and transport parameters of ions. The expression of the I/E response for linear sweep voltammetry and cyclic voltammetry can also be deduced as a particular case of this equation. The general solution given here is formally similar to that obtained for the application of any multipotential step sequence to a system with a single polarizable interface, since the method followed here is based on the same premises.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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