Modular segmented hyperbranched copolymers
Literature Information
Patricia R. Bachler, Kaitlyn E. Forry, Chelsea A. Sparks, Michael D. Schulz, Kenneth B. Wagener, Brent S. Sumerlin
Modular segmented hyperbranched polymers, amenable to facile post-polymerization functionalization, were created via two distinct approaches. Self-condensing vinyl polymerization via reversible addition–fragmentation chain transfer (RAFT) polymerization and RAFT polymerization with a divinyl comonomer were employed to create well-defined highly branched materials containing activated esters amenable to highly efficient functionalization in a modular manner.
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