Heterogeneous chemistry of toluene, kerosene and diesel soots

Literature Information

Publication Date 2009-01-06
DOI 10.1039/B815400G
Impact Factor 3.676
Authors

Helen M. Daly, Andrew B. Horn


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Abstract

Soot samples as potential mimics of atmospheric aerosols have been produced from the combustion of toluene, kerosene and diesel in order to compare the nature of soot produced from a simpler material, toluene, with soots from the fuels kerosene and diesel. Characterisation of the soots using elemental analysis, infrared spectroscopy, solvent extraction, thermal desorption and electron microscopy techniques before and after reaction with ozone allows assessment of the reactivity of soots from these different fuels. Despite the production of toluene and kerosene soots from identical combustion conditions, strong differences in structure and reactivity are observed in terms of their reaction with ozone. However, toluene soot is a much better mimic of diesel soot. It is proposed that the differing reactivities of the soots is related to the nature of the organic carbon and structure of the elemental carbon which vary with soots from the different fuels.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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