Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of TiNNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

Literature Information

Publication Date 2008-09-23
DOI 10.1039/B813911C
Impact Factor 6.222
Authors

Jonathan D. Selby, Christian Schulten, Andrew D. Schwarz, Andreas Stasch, Eric Clot, Cameron Jones, Philip Mountford


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Abstract

The first structurally authenticated [2+2] cycloaddition products of any transition metal hydrazide complexes are reported; cycloaddition products of transition metal hydrazides with alkynes and heteroalkynes have been obtained for the first time; these are the first structurally authenticated cycloaddition products for any transition metal MNNR2 functional group.

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