Chalcone derivatives as highly versatile photoinitiators for radical, cationic, thiol–ene and IPN polymerization reactions upon exposure to visible light
Literature Information
Publication Date
2013-08-20
DOI
10.1039/C3PY00922J
Impact Factor
5.582
Authors
Mohamad-Ali Tehfe, Frédéric Dumur, Pu Xiao, Marie Delgove, Bernadette Graff, Jean-Pierre Fouassier, Didier Gigmes, Jacques Lalevée
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Abstract
Chalcone derivatives are proposed as novel photoinitiators for polymerization upon exposure to visible light (even under soft irradiation conditions: blue LED bulb at 462 nm, halogen lamp, and sunlight). Remarkably, these structures are highly versatile allowing access to photoinitiating systems for (i) the free radical polymerization of acrylates, (ii) the cationic polymerization of epoxides and vinyl ethers, (iii) the synthesis of interpenetrated polymer networks (IPNs) and (iv) the thiol–ene processes. Excellent polymerization profiles are obtained. The initiation mechanisms are analyzed through ESR, steady state photolysis, cyclic voltammetry, laser flash photolysis and fluorescence experiments.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure](https://static.chemtradehub.com/structs/210/210532-98-2-f6a7.webp "S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure")
S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine
CAS Number:
210532-98-2
Molecular Formula:
C53H83NO8S
2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride
CAS Number:
1329799-67-8
Molecular Formula:
C7H2ClD6NO2
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