Quantitative formation of a tetraporphyrin [2]catenaneviacopper and zinc coordination
Literature Information
Maryline Beyler, Valérie Heitz, Jean-Pierre Sauvage
A [2]catenane is formed quantitatively by mixing substituted 1,10-phenanthroline-based chelates with copper(I) acting as central template, the ring-forming reaction being based on the coordination of pyridinic bidentate ligands onto the zinc atoms of the four porphyrins surrounding the core of the molecule.
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