Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction

Literature Information

Publication Date 2008-09-24
DOI 10.1039/B810574J
Impact Factor 6.222
Authors

Pascal D. C. Dietzel, Rune E. Johnsen, Helmer Fjellvåg, Silvia Bordiga, Elena Groppo, Sachin Chavan, Richard Blom


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Abstract

The microporous metal–organic framework Ni2(dhtp) (H4dhtp = 2,5-dihydroxyterephthalic acid) shows distinct end-on CO2 coordination to coordinatively unsaturated nickel sites giving rise to high CO2 adsorption capacity at sub-atmospheric pressures and ambient temperatures.

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