Asymmetric synthesis of either diastereomer of trifluoromethylated allylic amines by the selective reduction of trifluoromethyl α,β-unsaturated N-tert-butanesulfinyl ketoimines
Literature Information
Publication Date
2008-09-12
DOI
10.1039/B810459J
Impact Factor
6.222
Authors
Zhen-Jiang Liu, Jin-Tao Liu
View Original
Abstract
Regio- and diastereoselective reduction of chiraltrifluoromethyl α,β-unsaturated N-tert-butanesulfinyl ketoimines 1 was achieved by choosing appropriate reducing agent and either diastereomer of the corresponding trifluoromethylated allylic amines was obtained with good yield and excellent diastereoselectivity (up to >99 : 1 dr).
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Chemical Communications
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