An efficient heteropolyacid catalyzed acylation of pyruvate esters to α-acyloxyacrylate esters as potential candidate monomers for bio-based polymers
Literature Information
Masahiro Sadakane, Shinji Matsuoka, Hiroki Nakamura, Hiroyuki Naitou, Wataru Ueda
α-Acyloxyacrylate esters were efficiently synthesized from pyruvate esters and carboxylic anhydrides under mild conditions. These esters are potential candidate monomers for bio-based polymers with high durability and transparency. Tungsten-based Keggin type heteropolyacids, especially H3PW12O40, worked more effectively as catalysts for this reaction than other typical acids.
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![2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure 2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure](https://static.chemtradehub.com/structs/877/877395-58-9-70bf.webp)


