Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes

Literature Information

Publication Date 2008-09-17
DOI 10.1039/B809937E
Impact Factor 6.222
Authors

Motonori Abe, Kazuyuki Kamo, Yusuke Kosako


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Abstract

Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3,η2,η3,η5-acenaphthylene)Ru3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.

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