Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes
Literature Information
Motonori Abe, Kazuyuki Kamo, Yusuke Kosako
Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3,η2,η3,η5-acenaphthylene)Ru3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.
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