Dendrimer design using CuI-catalyzed alkyne–azide “click-chemistry”
Literature Information
Publication Date
2008-09-17
DOI
10.1039/B809870K
Impact Factor
6.222
Authors
Grégory Franc, Ashok Kakkar
View Original
Abstract
The chemoselective [3+2] cycloaddition of an azide on to an alkyne, catalyzed by Cu1, has become known as “click-chemistry”. The ease with which this reaction can be carried out and the formation of pure product without the need for further purification, offer a tremendous potential in developing monodisperse 1,4-disubstituted 1,2,3-triazole heterocycle based macromolecules of a diverse nature. The versatility of this approach in designing dendrimers or functionalizing them at the periphery with desired molecules has rekindled hopes in developing nanomaterials, at scales that can accelerate their entry into industrial usage.
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Chemical Communications
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