Designed molecular propellers based on tetraarylterephthalamide and their chiroptical properties induced by biased helicity through transmission of point chirality
Literature Information
Ryo Katoono, Hidetoshi Kawai, Kenshu Fujiwara, Takanori Suzuki
The syn-atropisomers of the title bis(tertiary amide)s were designed as six-bladed molecular propellers based on the “directing effects” of amide dipoles; the helicity of the propeller is biased to prefer one handedness upon the attachment of point chirality to the amide nitrogens to attain stronger circular-dichroism activity than for the non-propeller-shaped anti-isomers.
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