Single-crystal to single-crystal phase transition of cucurbit[5]uril hydrochloridehydrates: large water-filled channels transforming to layers of unusual stability

Literature Information

Publication Date 2008-08-27
DOI 10.1039/B807033D
Impact Factor 6.222
Authors

David Bardelang, Konstantin A. Udachin, Roberto Anedda, Igor Moudrakovski, Donald M. Leek, John A. Ripmeester, Christopher I. Ratcliffe


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Abstract

Cucurbit[5]uril hydrochloride hydrate crystals with large water-filled channels transform to a highly stable layer structure via a single-crystal to single-crystal mechanism; 129Xe NMR showed that porosity in CB[5] samples depends critically on the method of preparation.

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