Polycarbide nickel clusters containing interstitial Ni(η2-C2)4 and Ni2(μ-η2-C2)4 acetylide moieties: mimicking the supersaturated Ni–C solutions preceding the catalytic growth of CNTs with the structures of [HNi25(C2)4(CO)32]3− and [Ni22(C2)4(CO)28Cl]3−
Literature Information
Cristina Femoni, Maria Carmela Iapalucci, Giuliano Longoni, Stefano Zacchini
Reaction of [Ni6(CO)12]2− with CCl4 in CH2Cl2 gives the [HNi25(C2)4(CO)32]3− and [Ni22(C2)4(CO)28Cl]3−carbonyl clusters containing interstitial Ni(η2-C2)4 and Ni2(μ-η2-C2)4 acetylide moieties.
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![2-{[(1R,2S)-2-Aminocyclohexyl]amino}-4-{[3-(2H-1,2,3-triazol-2-yl)phenyl]amino}-5-pyrimidinecarboxamide structure 2-{[(1R,2S)-2-Aminocyclohexyl]amino}-4-{[3-(2H-1,2,3-triazol-2-yl)phenyl]amino}-5-pyrimidinecarboxamide structure](https://static.chemtradehub.com/structs/137/1370261-96-3-40df.webp)