Isolation of an [SNS]Pd(ii) pincer with a water ladder and its Suzuki coupling activity in water

Literature Information

Publication Date 2008-04-29
DOI 10.1039/B802043D
Impact Factor 6.222
Authors

Shi-Qiang Bai, T. S. Andy Hor


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Abstract

A water-compatible Pd(II) pincer with a hybrid [SNS]-donor set, [L1PdCl]Cl·2H2O [L1 = bis-(2-(i-butylsulfanyl)-ethyl)-amine] has been isolated and crystallographically characterized; its solid lattice at 223 K contains a ladder-like water polymer of tetramers and extensive H-bonding exists among the cation, anion and water cluster, and this water-soluble complex is active in Suzuki–Miyaura coupling of phenylboronic acid and selected aryl bromides in water at 75 °C.

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DOI: 10.1039/C7CP90112G

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