Isolation of an [SNS]Pd(ii) pincer with a water ladder and its Suzuki coupling activity in water
Literature Information
Shi-Qiang Bai, T. S. Andy Hor
A water-compatible Pd(II) pincer with a hybrid [SNS]-donor set, [L1PdCl]Cl·2H2O [L1 = bis-(2-(i-butylsulfanyl)-ethyl)-amine] has been isolated and crystallographically characterized; its solid lattice at 223 K contains a ladder-like water polymer of tetramers and extensive H-bonding exists among the cation, anion and water cluster, and this water-soluble complex is active in Suzuki–Miyaura coupling of phenylboronic acid and selected aryl bromides in water at 75 °C.
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