Component exchange as a synthetically advantageous strategy for the preparation of bicyclic cage compounds

Literature Information

Publication Date 2008-03-14
DOI 10.1039/B801299G
Impact Factor 6.222
Authors

Mateo Alajarín, José Berná, Carmen López-Leonardo, Jonathan W. Steed


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Abstract

Macrobicyclic triphosphazides are able to reversibly exchange one of their tripodal components by means of a dynamic disassembly–reassembly process; surprisingly this strategy provides better yields of cage compounds than a direct tripod–tripod coupling.

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Chemical Communications

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